Figure 2. Low-volume air sampler locations.
Third Quarter 2004
INEEL Quarterly Site Environmental Report
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The primary pathway by which radionuclides can move off the INEEL is through the air and for this reason the air pathway is the primary focus of monitoring on and around the INEEL. Samples for particulates and iodine-131 (131I) gas in air were collected weekly at 16 locations using low-volume air samplers for the duration of the quarter. Moisture in the atmosphere was sampled at four locations around the INEEL and analyzed for tritium. Concentrations of airborne particulates less than 10 micrometers in diameter (PM10) were measured for comparison with EPA standards at three locations. Air sampling activities and results for the third quarter, 2004 are discussed below. A summary of approximate minimum detectable concentrations (MDCs) for radiological analyses and DOE Derived Concentration Guide (DCG) (DOE 1993) values is provided in Appendix B.
Radioactivity associated with airborne particulates was monitored continuously by 18 low-volume air samplers (two of which are used as replicate samplers) at 16 locations during the third quarter of 2004 (Figure 2). Three of these samplers are located on the INEEL, nine are situated off the INEEL near the boundary, and six have been placed at locations distant to the INEEL. Samplers are divided into INEEL, Boundary, and Distant groups to determine if there is a gradient of radionuclide concentrations, increasing towards the INEEL. Each replicate sampler is relocated every year to a new location. One replicate sampler was placed at the Blackfoot Community Monitoring Station (CMS) (Distant location) and one at Mud Lake (Boundary location) during 2004. An average of 14,643 ft3 (415 m3) of air was sampled at each location, each week, at an average flow rate of 1.45 ft3/min (0.04 m3/min). Particulates in air were collected on glass fiber particulate filters (1.2 µm pore size). Gases passing through the filter were collected with an activated charcoal cartridge.
Figure 2. Low-volume air sampler locations.
The weekly particulate filters collected during the quarter for each location were composited and analyzed for gamma-emitting radionuclides. Composites were also analyzed by location for 90Sr, or 238Pu, 239/240Pu, and 241Am as determined by a rotating quarterly schedule.
Charcoal cartridges were analyzed for gamma-emitting radionuclides, specifically for 131I. Iodine-131 is of particular interest because it is produced in relatively large quantities by nuclear fission, is readily accumulated in human and animal thyroids, and has a half-life of eight days. This means that any elevated level of 131I in the environment could be from a recent release of fission products.
Gross alpha results are reported in Table C-1. Median gross alpha concentrations in air for INEEL, Boundary, and Distant locations for the third quarter of 2004 are shown in Figure 3. The data were tested for normality prior to statistical analyses. For the most part the data showed no discernable distribution. Box and whisker plots are commonly used when there is no assumed distribution.
Each data group in Figure 3 is presented as a box and whisker plot, with a median, a box enclosing values between the 25th and 75th percentiles, and whiskers representing the non-outlier range. Note that outliers and extreme values are identified separately from the box and whiskers. Outliers and extreme values are atypical, infrequent, data points that are far from the middle of the data distribution. For this report, outliers are defined as values that are greater than 1.5 times the height of the box, above or below the box. Extreme values are greater than 2 times the height of the box, above or below the box. Outliers and extreme values may reflect inherent variability, may be due to errors associated with transcription or measurement, or may be related to other anomalies. A careful review of the data collected during the third quarter indicates that the outliers and extreme values were not due to mistakes in collection, analysis, or reporting procedures, but rather reflect natural variability in the measurements. The outliers and extreme values lie within the range of measurements made within the past five years. Thus, rather than dismissing the outliers, they were included in the subsequent statistical analyses. Further discussion of box plots may be found in Determining Statistical Differences under Helpful Information.
Figure 3 graphically shows that the gross alpha measurements made at INEEL, Boundary, and Distant locations are similar for the third quarter. If the INEEL were a significant source of offsite contamination, concentrations of contaminants should be statistically greater at Boundary locations than at Distant locations. Because there is no discernable distribution of the data, the nonparametric Kruskal-Wallis test of multiple independent groups was used to test for statistical differences between INEEL, Boundary, and Distant locations. The use of nonparametric tests, such as Kruskal-Wallis, gives less weight to outliers and extreme values thus allowing a more appropriate comparison of data groups. A statistically significant difference exists between data groups if the (p) value is less than 0.05. Values greater than 0.05 translate into a 95 percent confidence that the medians are statistically the same. The p value for each comparison is shown in Table D-1. There were no statistical differences in gross alpha concentrations between groups for the third quarter.
Comparisons of gross alpha concentrations were made for each month of the quarter (Figure 4, Figure 5, and Figure 6). Again the Kruskal-Wallis test of multiple independent groups was used to determine if statistical differences exist between INEEL, Boundary, and Distant data groups. There were no statistical differences in gross alpha between groups for any month (Table D-1).
As an additional check, comparisons between gross alpha concentrations measured at Boundary and Distant locations were made on a weekly basis. The Mann-Whitney U test was used to compare the Boundary and Distant data because it is the most powerful nonparametric alternative to the t-test for independent samples. INEEL sample results were not included in this analysis because the onsite data, collected at only three locations, are not representative of the entire INEEL and would not aid in determining offsite impacts. Gross alpha concentrations measured at Boundary locations were not statistically different than those measured at Distant locations for any week of the quarter (Table D-2). More detail on the statistical tests used can be found in Determining Statistical Differences under Helpful Information.
Gross beta results are also presented in Table C-1. Gross beta concentrations in air for INEEL, Boundary, and Distant locations for the third quarter of 2004 are shown in Figure 7 The data were tested and found to be neither normally nor log-normally distributed. Box and whiskers plots were used for presentation of the data. Outliers and extreme values were retained in subsequent statistical analyses because they are within the range of measurements made in the past five years, and because these values could not be attributed to mistakes in collection, analysis, or reporting procedures. As in the case of alpha activity, the quarterly data for each group appear to be similar and were determined, using the Kruskal-Wallace test, to be statistically the same (Table D-1).
Monthly median gross beta concentrations in air for each sampling group are shown in Figure 8, Figure 9, and Figure 10. Statistical data are presented in Table D-1. There were no statistical differences in gross beta between groups for any month during the quarter (Table D-1).
Comparison of weekly Boundary and Distant data sets, using the Mann Whitney U test, indicates a difference between the two location groups for the weeks of August 11 and September 29, 2004 (Table D-2). In both instances the Boundary group was statistically greater than the Distant group for the week. Analysis for each week by Boundary location group and Distant location group showed no statistical difference between stations. In other words no one or group of stations appeared to be significantly higher or lower than the other stations. Thus, it is interpreted that the statistical difference is a result of natural variability.
No 131I was measured above the 3s value in any of the charcoal cartridge batches during the quarter. Weekly 131I results for each location are listed in Table C-2 of Appendix C.
Weekly filters for the third quarter of 2004 were composited by location and analyzed for gamma-emitting radionuclides, including cesium-137 (137Cs). Selected composites were also analyzed for 90Sr, 238Pu, 239/240Pu, and 241Am. The concentrations measured during this quarter are consistent with those recorded in the past. All results were far less than their respective DCGs. Two composite samples, collected at Blackfoot and Mud Lake (Q/A-2), had 241Am measurements that were greater than their 3s uncertainty values. Both were duplicate measurements at these locations and the corresponding duplicate measurements did not exceed the 3s values. The maximum value, measured at Blackfoot, was (5.44 ± 1.40) × 10-12 pCi/mL ([2.01 ± 0.52] × 10-13 Bq/mL). The Derived Concentration Guide for 241Am is 2 x 10-8 pCi/mL. One 90Sr result, (3.35 ± 1.11) × 10-11 pCi/mL ([1.24 ± 0.41] × 10-12 Bq/mL), obtained from Monteview, exceeded its 3s uncertainty value. The Derived Concentration Guide for 90Sr is 5 x 10-5 pCi/mL . The remaining radionuclides of interest, 137Cs, 238Pu, and 239/240Pu, were not detected in any composite sample. All results for composite filter samples are shown in Table C-3, Appendix C.
Fourteen atmospheric moisture samples were collected using silica gel and fifteen samples were collected using molecular sieve material during the third quarter of 2004. Samples were grouped as follows: six each from Atomic City and Idaho Falls, eight from Rexburg and nine from Blackfoot. Atmospheric moisture is collected by pulling air through a column of absorbent material (i.e., silica gel or molecular sieve) to absorb water vapor. The water is then extracted from the absorbent material by heat distillation. The resulting water samples are then analyzed for tritium using liquid scintillation.
Four of the samples exceeded their respective 3s values (two from Atomic City, and one each from Blackfoot and Rexburg). Two of these samples were collected using silica gel and two were collected using molecular sieve. All sample results were well below the DOE DCG for tritium in air of 1 X 10-7 mCi/mL (3.7 x 10-3 Bq/mL). The maximum value was (7.36 ± 2.09) x 10-13 mCi/mL of air ([2.72 ± 0.77] x 10-8 Bq/mL of air). All results for atmospheric moisture samples are shown in Table C-4, Appendix C.
The EPA began using a standard for concentrations of airborne particulate matter (PM) less than 10 micrometers in diameter (PM10) in 1987 (40 CFR 50.6, 1996). Particles of this size can be inhaled deep into the lungs and are considered to be responsible for most of the adverse health effects associated with airborne particulate pollution. The air quality standards for these particulates are an annual average of 50 µg/m3, with a maximum 24-hour concentration of 150 µg/m3.
The ESER Program operates three PM10 samplers, one each at the Rexburg CMS and Blackfoot CMS, and in Atomic City. Sampling of PM10 is informational only as no chemical analyses are conducted for contaminants. A twenty-four hour sampling period is scheduled to run once every six days. Equipment problems nullified one sample from the Rexburg location. The maximum 24-hour concentration was 84.9 µg/m3 on September 11, 2004, at Atomic City. The average, maximum, and minimum results of the 24-hour samples are summarized in Table 1. None of the results exceeds the maximum 24-hour air quality standard established by EPA of 150 µg/m3. Results for all PM10 samples are listed in Table C-5, Appendix C.
Table 1. Summary of 24-hour PM10 values.
|
|
Concentrationa |
||
|
Location |
Minimum |
Maximum |
Average |
|
Atomic City |
3.83 |
84.88 |
26.64 |
|
Blackfoot, CMS |
2.04 |
35.22 |
18.50 |
|
Rexburg, CMS |
7.07 |
39.76 |
22.92 |
|
a. All concentrations are in (mg/m3). |
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